Publications

(268) view "Calcium Coordination Solids for pH-Triggered Release of Olsalazine" Levine, D. J.; Gonzalez, M. I.; Legendre, C. M.; Runčevski, T.; Oktawiec, J.; Colwell, K. A.; Long, J. R. ChemMedChem 2017.

(267) view "A Diaminopropane-Appended Metal–Organic Framework Enabling Efficient CO2 Capture from Coal Flue Gas via a Mixed Adsorption Mechanism" Milner, P. J.; Siegelman, R. L.; Forse, A. C.; Gonzalez, M. I.; Runčevski, T.; Martell, J. D.; Reimer, J. A.; Long, J. R. J. Am. Chem. Soc. 2017.

(266) view "A Spin Transition Mechanism for Cooperative Adsorption in Metal–Organic Frameworks" Reed, D. A.; Keitz, B. K.; Oktawiec, J.; Mason, J. A.; Runčevski, T.; Xiao, D. J.; Darago, L. E.; Crocellà, V.; Bordiga, S.; Long, J. R. Nature 2017.

(265) view "Ta(CNDipp)6: An Isocyanide Analogue of Hexacarbonyltantalum(0)" Chakarawet, K.; Davis-Gilbert, Z. W.; Harstad, S. R.; Young, V. G.; Long, J. R.; Ellis, J. E. Angew. Chem. 2017, 56, 10577-10581.

(264) view "Controlling Cooperative CO2 Adsorption in Diamine-Appended Mg2(dobpdc) Metal–Organic Frameworks" Siegelman, R. L.; McDonald, T. M.; Gonzalez, M. I.; Martell, J. D.; Milner, P. J.; Mason, J. A.; Berger, A. H.; Bhown, A. S.; Long, J. R. J. Am. Chem. Soc. 2017, 139, 10526-10538.

(263) view "Performance of van der Waals Corrected Functionals for Guest Adsorption in the M2(dobdc) Metal–Organic Frameworks" Vlaisavljevich, B.; Huck, J.; Hulvey, Z.; Lee, K.; Mason, J. A.; Neaton, J. B.; Long, J. R.; Brown, C. M.; Alfè, D.; Michaelides, A.; Smit, B. J. Phys. Chem. A 2017, 121, 4139-4151.

(262) view "Highly effective ammonia removal in a series of Brønsted acidic porous polymers: investigation of chemical and structural variations" Barin, G.; Peterson, G. W.; Crocellà, V.; Xu, J.; Colwell, K. A.; Nandy, A.; Reimer, J. A.; Bordiga, S.; Long, J. R. Chem. Sci. 2017, 8, 4399-4409.

(261) view "Structural characterization of framework–gas interactions in the metal–organic framework Co2(dobdc) by in situ single-crystal X-ray diffraction" Gonzalez, M. I.; Mason, J. A.; Bloch, E. D.; Teat, S. J.; Gagnon, K. J.; Morrison, G. Y.; Queen, W. L.; Long, J. R. Chem. Sci. 2017, 8, 4387-4398.

(260) view "A Microporous Amic Acid Polymer for Enhanced Ammonia Capture" Lee, J.; Barin, G.; Peterson G. W.; Xu, J.; Colwell, K. A.; Long, J. R. ACS Appl. Mater. Interfaces 2017.

(259) view "Ethylene Oligomerization in Metal–Organic Frameworks Bearing Nickel(II) 2,2′-Bipyridine Complexes" Gonzalez, M. I.; Oktawiec, J.; Long, J. R. Faraday Discuss. 2017, 201, 351-367.

(258) view "Magneto-Structural Correlations in Pseudotetrahedral Forms of the [Co(SPh)4]2– Complex Probed by Magnetometry, MCD Spectroscopy, Advanced EPR Techniques, and ab Initio Electronic Structure Calculations" Suturina, E. A.; Nehrkorn, J.; Zadrozny, J. M.; Liu, J.; Atanasov, M.; Weyhermüller, T.; Maganas, T.; Hill, S.; Schnegg, A.; Bill, E.; Long, J. R.; Neese, F. Inorg. Chem. 2017, 56, 3102-3118.

(257) view "A Trinuclear Radical-Bridged Lanthanide Single-Molecule Magnet" Gould, C. A.; Darago, L. E.; Gonzalez, M. I.; Demir, S.; Long, J. R. Angewandte Chemie 2017.

(256) view "Techno-economic Analysis of Metal−Organic Frameworks for Hydrogen and Natural Gas Storage" DeSantis, D.; Mason, J. A.; James, B. D.; Houchins, C.; Long, J. R.; Veenstra, M. Energy & Fuels 2017, 31, 2024-2032.

(255) view "Perspectives on Neutron Scattering in Lanthanide-Based Single-Molecule Magnets and a Case Study of the Tb2(μ-N2) System" Prša, K.; Nehrkorn, J.; Corbey, J. F.; Evans, W. J.; Demir, S.; Long, J. R.; Guidi, T.; Waldmann, O. Magnetochemistry 2016, 2, 45.

(254) view "Tuning the Adsorption-Induced Phase Change in the Flexible Metal−Organic Framework Co(bdp)" Taylor, M. K.; Runčevski, T.; Oktawiec, J.; Gonzalez, M. I.; Siegelman, R. L.; Mason, J. A.; Ye, J.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2016, 138, 15019-15026.

(253) view "Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe2(dobdc) Analogues" Xiao, D. J.; Oktawiec, J.; Milner, P. J.; Long, J. R. J. Am. Chem. Soc. 2016, 138, 14371-14379.

(252) view "Multifaceted Magnetization Dynamics in the Mononuclear Complex [ReIVCl4(CN)2]2−" Feng, X.; Liu, J.; Pedersen, K. S.; Nehrkorn, J.; Schnegg, A.; Holldack, K.; Bendix, J.; Sigrist, M.; Mutka, H.; Samohvalov, D.; Aguila, D.; Tong, M.; Long, J. R.; Clerac, R. Chem. Commun. 2016, 52, 12905-12908.

(251) view "Cobalt Polypyridyl Complexes as Transparent Solution-Processable Solid-State Charge Transport Materials" Kashif, M. K.; Milhuisen, R. A.; Nippe, M.; Hellerstedt, J.; Zee, D. Z.; Duffy, N. W.; Halstead, B.; De Angelis, F.; Fantacci, S.; Fuhrer, M. S.; Chang, C. J.; Cheng, Y.; Long, J. R.; Spiccia, L.; Bach, U. Adv. Energy Mater. 2016, 1600874.

(250) view "Accelerated Computational Analysis of Metal−Organic Frameworks for Oxidation Catalysis" Vogiatzis, K. D.; Haldoupis, E.; Xiao, D. J.; Long, J. R.; Siepmann, J. I.; Gagliardi, L. J. Phys. Chem. C 2016, 120, 18707-18712.

(249) view "Olsalazine-Based Metal−Organic Frameworks as Biocompatible Platforms for H2 Adsorption and Drug Delivery" Levine, D.J.; Runčevski, T.; Kapelewski, M. K.; Keitz, B. K.; Oktawiec, J.; Reed, D. A.; Mason, J. A.; Jiang, H. Z. H.; Colwell, K. A.; Legendre, C. M.; FitzGerald, S. A.; Long, J. R. J. Am. Chem. Soc. 2016, 138, 10143-10150.

(248) view "Hydrogen Storage and Selective, Reversible O2 Adsorption in a Metal–Organic Framework with Open Chromium(II) Sites" Bloch, E. D.; Queen, W. L.; Hudson, W. R.; Mason, J. A.; Xiao, D. J.; Murray, L. J.; Flacau, R.; Brown, C. M.; Long, J. R. Angew. Chem. Int. Ed. 2016, 55, 8605-8609.

(247) view "Synthesis and Characterization of a Tetrapodal NO44– Ligand and Its Transition Metal Complexes" Axelson, J. C.; Gonzalez, M. I.; Meihaus, K. R.; Chang, C. J.; and Long, J. R. Inorg. Chem. 2016, 55, 7527−7534.

(246) view "Enhanced Ethylene Separation and Plasticization Resistance in Polymer Membranes Incorporating Metal–Organic Framework Nanocrystals" Bachman, J. E.; Smith, Z. P.; Li, T.; Xu, T.; Long, J. R. Nat. Mater. 2016, 15, 845-849.

(245) view "Copper Capture in a Thioether-Functionalized Porous Polymer Applied to the Detection of Wilson’s Disease" Lee, S.; Barin, G.; Ackerman, C. M.; Muchenditsi, A.; Xu, J.; Reimer, J. A.; Lutsenko, S.; Long, J. R.; Chang, C. J. J. Am. Chem. Soc. 2016, 138, 7603-7609.

(244) view "Adsorption of Two Gas Molecules at a Single Metal Site in a Metal-Organic Framework" Runčevski, T.; Kapelewski, M. T.; Torres-Gavosto, R. T.; Tarver, J. D.; Brown, C. M.; Long, J. R. Chem. Commun. 2016, 52, 8251-8254.

(243) view "Selective, Tunable O2 Binding in Cobalt(II)−Triazolate/Pyrazolate Metal−Organic Frameworks" Xiao, D. J.; Gonzalez, M. I.; Darago, L. E.; Vogiatzis, K. D.; Haldoupis, E.; Gagliardi, L.; Long, J. R. J. Am. Chem. Soc. 2016, 138, 7161-7170.

(242) view "Plasticization-resistant Ni2(dobdc)/polyimide Composite Membranes for the Removal of CO2 from Natural Gas" Bachman, J. E.; Long, J. R. Energy Environ. Sci. 2016, 9, 2031-2036.

(241) view "A Computational Study of CH4 Storage in Porous Framework Materials with Metalated Linkers: Connecting the Atomistic Character of CH4 Binding Sites to Usable Capacity" Tsivion, E.; Mason, J. A.; Gonzalez, M. I.; Long, J. R.; Head-Gordon, M. Chem. Sci. 2016, 7, 4503-4518.

(240) view "Structural and Electronic Effects on the Properties of Fe2(dobdc) upon Oxidation with N2O" Borycz, J.; Paier, J.; Verma, P.; Darago, L. E.; Xiao, D. J.; Truhlar, D. G.; Long, J. R.; Gagliardi, L. Inorg. Chem. 2016, 55, 4924-4934.

(239) view "Reversible CO Scavenging via Adsorbate-Dependent Spin State Transitions in an Iron(II)–Triazolate Metal–Organic Framework" Reed, D. A.; Xiao, D. J.; Gonzalez, M. I.; Darago, L. E.; Herm, Z. R.; Grandjean, F.; Long, J. R. J. Am. Chem. Soc. 2016, 138, 5594-5602.

(238) view "Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework" Demir, S.; Brune, N. K.; Van Humbeck, J. F.; Mason, J. A.; Plakhova, T. V.; Wang, S.; Tian, G.; Minasian, S. G.; Tyliszczak, T.; Yaita, T.; Kobayashi, T.; Kalmykov, S. N.; Shiwaku, H.; Shuh, D. K.; Long, J. R. ACS Cent. Sci. 2016, 2, 253–265.

(237) view "Hydrogen Storage in the Expanded Pore Metal–Organic Frameworks M2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn)" Gygi, D.; Bloch, E. D.; Mason, J. A.; Hudson, M. R.; Gonzalez, M. I.; Siegelman, R. L.; Darwish, T. A.; Queen, W. L.; Brown, C, M.; Long, J. R. Chem. Mater. 2016, 28, 1128-1138.

(236) view "Homoleptic Two-Coordinate Silylamido Complexes of Chromium(I), Manganese(I), and Cobalt(I)" Werncke, C. G.; Suturina, E.; Bunting, P. C.; Vendier, L.; Long, J. R.; Atanasov, M.; Neese, F.; Sabo-Etienne, S.; Bontemps, S. Chem. Eur. J. 2016, 22, 1668-1674.

(235) view "Expanding the Chemistry of Molecular U2+ Complexes: Synthesis, Characterization, and Reactivity of the {[C5H3(SiMe3)2]3U} Anion" Windorff, C. J.; MacDonald, M. R.; Meihaus, K. R.; Ziller, J. W.; Long, J. R.; Evans, W. J. Chem. Eur. J. 2016, 22, 772-782.

(234) view "Dinuclear Cobalt Complexes with a Decadentate Ligand Scaffold: Hydrogen Evolution and Oxygen Reduction Catalysis" Di Giovanni, C.; Gimbert-Suriñach, C.; Nippe, M.; Benet-Buchholz, J.; Long, J. R.; Sala, X.; Llobet, A. Chem. Eur. J. 2016, 22, 361-369.

(233) view "Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal−Organic Framework" Darago, L. E.; Aubrey, M. L.; Yu, C. J.; Gonzalez, M. I.; Long, J. R. J. Am. Chem. Soc. 2015, 137, 15703–15711.

(232) view "Influence of Solvent-Like Sidechains on the Adsorption of Light Hydrocarbons in Metal–Organic Frameworks" Schneemann, A.; Bloch, E. D.; Henke, S.; Llewellyn, P. L.; Long, J. R.; Fischer, R. A. Chem. Eur. J. 2015, 21, 18764–18769.

(231) view "Sub-micron Polymer–Zeolitic Imidazolate Framework Layered Hybrids via Controlled Chemical Transformation of Naked ZnO Nanocrystal Films" Meckler, S. M.; Li, C.; Queen, W. L.; Williams, T. E.; Long, J. R.; Buonsanti, R.; Milliron, D. J.; Helms, B. A. Chem. Mater. 2015, 27, 7673-7679.

(230) view "A Dual−Ion Battery Cathode via Oxidative Insertion of Anions in a Metal–Organic Framework" Aubrey, M. L.; Long, J. R. J. Am. Chem. Soc. 2015, 137, 13594–13602.

(229) view "Methane Storage in Flexible Metal-Organic Frameworks with Intrinsic Thermal Management" Mason, J. A.; Oktawiec, J.; Taylor, M. K.; Hudson, M. R.; Rodriguez, J.; Bachman, J. E.; Gonzalez, M. I.; Cervellino, A.; Guagliardi, A.; Brown, C. M.; Llewellyn, P. L.; Masciocchi, N.; Long, J. R. Nature 2015, 527, 357-361.

(228) view "Isolation of +2 Rare Earth Metal Ions with Three Anionic Carbocyclic Rings: Bimetallic Bis(cyclopentadienyl) Reduced Arene Complexes of La2+ and Ce2+ are Four Electron Reductants" Kotyk, C. M.; Fieser, M. E.; Palumbo, C. T.; Ziller, J. W.; Darago, L. E.; Long, J. R.; Furche, F.; Evans, W. J. Chem. Sci. 2015, 6, 7267-7273

(227) view "Synthesis and O2 Reactivity of a Titanium(III) Metal-Organic Framework" Mason, J. A.; Darago, L. E.; Lukens, W. W.; Long, J. R. Inorg. Chem. 2015, 54, 10096–10104.

(226) view "Critical Factors Driving the High Volumetric Uptake of Methane in Cu3(btc)2" Hulvey, Z.; Vlaisavljevich, B.; Mason, J. A.; Tsivion, E.; Dougherty, T. P.; Bloch, E. D.; Head-Gordon, M.; Smit, B.; Long, J. R.; Brown, C. M. J. Am. Chem. Soc. 2015, 137, 10816-10825.

(225) view "Probing the Mechanism of CO2 Capture in Diamine-Appended Metal-Organic Frameworks Using Measured and Simulated X-ray Spectroscopy" Drisdell, W. S.; Poloni, R.; McDonald, T. M.; Pascal, T. A.; Wan, L. F.; Pemmaraju, C. D.; Vlaisavljevich, B.; Odoh, S. O.; Neaton, J. B.; Long, J. R.; Prendergast, D.; Kortright, J. B. Phys. Chem. Chem. Phys. 2015, 17, 21448-21457.

(224) view "Record High Single-Ion Magnetic Moments through 4fn5d1 Electron Configurations in the Divalent Lanthanide Complexes" Meihaus, K. R; Fieser, M. E.; Corbey, J. J.; Evans, W. J.; Long, J. R. J. Am. Chem. Soc. 2015, 137, 9855-9860.

(223) view "Tetraarylborate Polymer Networks as Single-Ion Conducting Solid Electrolytes" Van Humbeck, J. F.; Aubrey, M. L.; Alsbaiee, A.; Ameloot, R.; Coates, G. W.; Dichtel, W. R.; Long, J. R. Chem. Sci. 2015, 6, 5499-5505.

(222) view "Influence of Guest Exchange on the Magnetization Dynamics of Dilanthanide Single-Molecule-Magnet Nodes within a Metal–Organic Framework" Zhang, X.; Vieru, V.; Feng, X.; Liu, J; Zhang, Z.; Na, B.; Shi, W.; Wang, B.; Powell, A. K.; Chibotaru, L. F.; Gao, S.; Cheng, P.; Long, J. R. Angew. Chem. Int. Ed. 2015, 54, 9861-9865.

(221) view "Metal–Polypyridyl Catalysts for Electro- and Photochemical Reduction of Water to Hydrogen" Zee, D. Z.; Chantarojsiri, T.; Long, J. R.; Chang, C. J. Acc. Chem. Res. 2015, 48, 2027-2036.

(220) view "Bioinspired Design of Redox-Active Ligands for Multielectron Catalysis: Effects of Positioning Pyrazine Reservoirs on Cobalt for Electro- and Photocatalytic Generation of Hydrogen from Water" Jurss, J. W.; Khnayzer, R. S.; Panetier, J. A.; El Roz, K. A.; Nichols, E. M.; Head-Gordon, M.; Long, J. R.; Castellano, F. N.; Chang, C. J. Chem. Sci. 2015, 6, 4954-4972.

(219) view "Understanding Small-Molecule Interactions in Metal-Organic Frameworks: Coupling Experiment with Theory" Lee, J. S.; Vlaisavljevich, B.; Britt, D. K.; Brown, C. M.; Haranczyk, M.; Neaton, J. B.; Smit, B.; Long, J. R.; Queen, W. L. Adv. Mater. Early View.

(218) view "Nickel(II) and Copper(I,II)-Based Metal-Organic Frameworks Incorperating an Extended Tris-Pyrazolate Linker" Tabacaru, A.; Galli, S.; Pettinari, C.; Masciocchi, N.; McDonald, T. M.; Long, J. R. Cryst. Eng. Comm. 2015, 17, 4992-5001.

(217) view "Water-Soluble Iron(IV)-Oxo Complexes Supported by Pentapyridine Ligands: Axial Ligand Effects on Hydrogen Atom and Oxygen Atom Transfer Reactivity." Chantarojsiri, T.; Sun, Y.; Long, J. R.; Chang, C. J. Inorg. Chem. 2015, 54, 5879-5887.

(216) view "Mechanism of Oxidation of Ethane to Ethanol at Iron(IV)-Oxo Sites in Magnesium-Diluted Fe2(dobdc)." Verma P.; Vogiatzis, K. D.; Planas, N.; Borycz, J.; Xiao, D. J.; Long, J. R.; Gagliardi, L.; Truhlar, D. G. J. Am. Chem. Soc. 2015, 137, 5770-5781.

(215) view "Carbohydrate-Mediated Purification of Petrochemicals." Holcroft, J. M.; Hartlieb, K. J.; Moghadam, P. Z.; Bell, J. G.; Barin, G.; Ferriss, D. P.; Bloch, E. D.; Algaradah, M. M.; Nassar, M. S.; Botros, Y. Y.; Thomas, K. M.; Long, J. R.; Snurr, R. Q.; Stoddart, J. F. J. Am. Chem. Soc. 2015, 137, 5706-5719.

(214) view "Application of a High-Throughput Analyzer in Evaluating Solid Adsorbents for Post-Combustion Carbon Capture via Multicomponent Adsorption of CO2, N2, and H2O." Mason, J. A.; McDonald, T. M.; Bae, T.-H.; Bachman, J. E.; Sumida, K.; Dutton, J. J.; Kaye, S. S.; Long, J. R. J. Am. Chem. Soc. 2015, 137, 4787-4803.

(213) view "Cooperative Insertion of CO2 in Diamine-Appended Metal-Organic Frameworks" McDonald, T. M.; Mason, J. A.; Kong, X.; Bloch, E. D.; Gygi, D.; Dani, A.; Crocella, V.; Giordanino, F.; Odoh, S. O.;Drisdell, W.; Vlaisavljevich, B.; Dzubak, A. L.; Poloni, R.; Schnell, S. K.; Planas, N.; Lee, K.; Pascal, T.; Wan, L. F.; Prendergast, D.; Neaton, J. B.; Smit, B.; Kortright, J. B.; Gagliardi, L.; Bordiga, S.; Reimer, J. A.; Long, J. R. Nature 2015, 519, 303-308.

(212) view "Rapidly Assessing the Activation Conditions and Porosity of Metal-Organic Frameworks using Thermogravimetric Analysis" McDonald, T. M.; Bloch, E. D.; Long, J. R. Chem. Commun. 2015, 51, 4985-4988.

(211) view "Thermodynamic Complexity of Carbon Capture in Alkylamine-Functionalized Metal-Organic Frameworks" Wu, D.; McDonald, T. M.; Quan, Z.; Ushakov, S. V.; Zhang, P.; Long, J. R.; Navrotsky, A. J. Mater. Chem. A 2015, 3, 4248-4254.

(210) view "Gradual Release of Strongly Bound Nitric Oxide from Fe2(NO)2(dobdc)" Bloch, E. D.; Queen, W. L.; Chavan, S.; Wheatley, P. S.; Zadrozny, J. M.; Morris, R.; Brown, C. M.; Lamberti, C.; Bordiga, S.; Long, J. R. J. Am. Chem. Soc. 2015, 137, 3466-3469.

(209) view "Radical Ligand-Containing Single-Molecule Magnets" Demir, S.; Jeon, I. R.; Long, J. R.; Harris, T. D. Coord. Chem. Rev. 2015, 289, 149-176.

(208) view "Single-Crystal-to-Single-Crystal Metalation of a Metal-Organic Framework: A Route Toward Structurally Well-Defined Catalysts" Gonzalez, M. I.; Bloch, E. D.; Mason, J. A.; Teat, S. J.; Long, J. R. Inorg. Chem. 2015, 54, 2995-3005.

(207) view "Mechanism of Scrapie Prion Precipitation with Phosphotungstate Anions" Levine, D. J.; Stohr, J.; Falese, L. E.; Ollesch, J.; Wille, H. W.; Prusiner, S. B.; Long, J. R. ACS Chem. Biol. 2015, 10, 1269-1277.

(206) view "Two-Coordinate Iron(I) Complex [Fe{N(SiMe3)2}2]-: Synthesis, Properties, and Redox Activity" Werncke, C. G.; Bunting, P. C.; Duhayon, C.; Long, J. R.; Bontemps, S.; Sabo-Etienne, S. Angew. Chem. Int. Ed. 2015, 54, 245-248.

(205) view "NMR Relaxation and Exchange in Metal-Organic Frameworks for Surface Area Screening" Chen, J. J.; Mason, J. A.; Bloch, E. D.; Gygi, D.; Long, J. R.; Reimer, J. A. Micropor. Mesopor. Mater. 2015, 205, 65-69.

(204) view "Counteranion Effects on the Catalytic Activity of Copper Salts Immobilized on the 2,2'-Bipyridine-Functionalized Metal-Organic Framework MOF-253" Valvekens, P.; Bloch, E. D.; Long, J. R.; Ameloot, R.; De Vos, D. E. Catalysis Today 2015, 246, 55-59.

(203) view "Hydrogen Physisorption on Metal-Organic Framework Linkers and Metalated Linkers: A Computation Study of the Factors That Control Binding Strength" Tsivion, E.; Long, J. R.; Head-Gordon, M. J. Am. Chem. Soc. 2014, 136, 17827-17835.

(202) view "Actinide-Based Single-Molecule Magnets" Meihaus, K. R.; Long, J. R. Dalton Trans. 2014, 44, 2517-2528.

(201) view "Comprehensive Study of Carbon Dioxide Adsorption in the Metal-Organic Frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn)" Queen, W. L.; Hudson, M. R.; Bloch, E. D.; Mason, J. A.; Gonzalez, M. I.; Lee, J. S.; Gygi, D.; Howe, J. D.; Lee, K.; Darwish, T. A.; James, M.; Peterson, V. K.; Teat, S. J.; Smit, B.; Neaton, J. B.; Long, J. R.; Brown, C. M. Chem. Sci. 2014, 5, 4569-4581.

(200) view " Exchange Coupling and Magnetic Blocking in Dilanthanide Complexes Bridged by the Multi-Electron Redox-Active Ligand 2,3,5,6-tetra(2-pyridil)pyrazine)" Demir, S.; Nippe, M.; Gonzalez, M. I.; Long, J. R. Chem. Sci. 2014, 5, 4701-4711.

(199) view "M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal-Organic Frameworks Exhibiting Increased Charge Density and Enhanced H2 Binding at the Open Metal Sites" Kapelewski, M. T.; Geier, S. J.; Hudson, M. R.; Stuk, D.; Mason, J. A.; Nelson, J. N.; Xiao, D. J.; Hulvey, Z.; Gilmour, E.; FitzGerald, S. A.; Head-Gordon, M.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2014, 136, 12119-12129.

(198) view "A Well-Defined Terminal Vanadium(III) Oxo Complex" King, A. E.; Nippe, M.; Atanasov, M.; Chantarojsiri, T.; Wray, C. A.; Bill, E.; Neese, F.; Long, J. R.; Chang, C. J. Inorg. Chem. 2014, 53, 11388-11399.

(197) view "Reversible CO Binding Enables Tunable CO/H2 and CO/N2 Separations in Metal-Organic Frameworks with Exposed Divalent Metal Cations" Bloch, E. D.; Hudson, M. R.; Mason, J. A.; Chavan, S.; Crocella, V.; Howe, J. D.; Lee, K.; Dzubak, A. L.; Queen, W. L.; Zadrozny, J. M.; Geier, S. J.; Lin, L. C.; Gagliardi, L.; Smit, B.; Neaton, J. B.; Bordiga, S.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2014, 136, 10752-10761.

(196) view "Large Spin-Relaxation Barriers for the Low Symmetry Organolanthanide Complexes [Cp*2Ln(BPh4)] (Cp* = pentamethylcyclopentadienyl; Ln = Tb, Dy)" Demir, S.; Zadrozny, J. M.; Long, J. R. Chem. Eur. J. 2014, 20, 9524-9529.

(195) view "Oxidation of Ethane to Ethanol by N2O in a Metal-Organic Framework with Coordinatively Unsaturated Iron(II) Sites" Xiao, D. J.; Bloch, E. D.; Mason, J. A.; Queen, W. L.; Hudson, M. R.; Planas, N.; Borycz, J.; Dzubak, A. L.; Verma, P.; Lee, K.; Bonino, F.; Crocella, V.; Yano, J.; Bordiga, S.; Truhlar, D. G.; Gagliardi, L.; Brown, C. M.; Long, J. R. Nature Chem. 2014, 6, 590-595.

(194) view "Lithographic Deposition of Patterned Metal-Organic Framework Coatings Using Photobase Generator" Keitz, B. K.; Yu, C. J.; Long, J. R.; Ameloot, R. Angew. Chem. Int. Ed. 2014, 53, 5561-5565.

(193) view "Influence of Pyrazolate vs N-Heterocyclic Carbene Ligands on the Slow Magnetic Relaxation of Homoleptic Trischelate Lanthanide(III) and Uranium(III) Complexes" Meihaus, K. R.; Minasian, S. G.; Lukens, W. W. Jr.; Kozimor, S. A.; Shuh, D. K.; Tyliszczak, T.; Long, J. R. J. Am. Chem. Soc. 2014, 136, 6056-6068.

(192) view "Towards a Comprehensive Understanding of Visible-Light Photogeneration of Hydrogen from Water Using Cobalt(II) Polypyridyl Catalysts" Khnayzer, R. S.; Thoi, V. S.; Nippe, M.; King, A. E.; Jurss, J. W.; El Roz, K. A.; Long, J. R.; Chang, C. J.; Castellano, F. N. Energy Environ. Sci. 2014, 7, 1477-1488 .

(191) view "Influence of an Inner-Sphere K+ Ion on the Magnetic Behavior of N23- Radical-Bridged Dilanthanide Complexes Isolated Using an External Magnetic Field" Meihaus, K. R.; Corbey, J. F.; Fang, M.; Ziller, J.W.; Long, J.R.; Evans, W. J. Inorg. Chem. 2014, 53, 3099-3107 .

(190) view "Ammonia Capture in Porous Organic Polymers Densely Functionalized with Bronsted Acid Groups" Van Humbeck, J. F.; McDonald, T. M.; Jing, X.; Wiers, B. M.; Zhu, G.; Long, J. R. J. Am. Chem. Soc. 2014, 136, 2432-2440.

(189) view "Selective Propene Oligomerization with Nickel(II)-Based Metal-Organic Frameworks" Mlinar, A. N.; Keitz, B. K.; Gygi, D.; Bloch, E. D.; Long, J. R.; Bell, A. T. ACS Catalysis 2014, 4, 717-721.

(188) view "Design of a Metal-Organic Framework with Enhanced Back Bonding for Separation of N2 and CH4" Lee, K.; Isley III, W. C.; Dzubak, A. L.; Verma, P.; Stoneburner, S. J.; Lin, L. C.; Howe, J. D.; Bloch, E. D.; Reed, D. A.; Hudson, M. R.; Brown, C. M.; Long, J. R.; Neaton, J. B.; Smit, B.; Cramer, C. J.; Truhlar, D. G.; Gagliardi, L. J. Am. Chem. Soc. 2014, 136, 698-704.

(187) view "Metal-Organic Frameworks as Solid Magnesium Electrolytes" Aubrey, M. L.; Ameloot, R.; Wiers, B. M.; Long, J. R. Energy Environ. Sci. 2014, 7, 667-671.

(186) view "Hydrocarbon Separations in Metal-Organic Frameworks" Herm, Z. R.; Bloch, E. D.; Long, J. R. Chem. Mater. 2014, 26, 323-338.

(185) view "Evaluating Metal–Organic Frameworks for Natural Gas Storage" Mason, J. A.; Veenstra, M.; Long, J. R. Chem. Sci. 2014, 5, 32-51.

(184) view "Probing Adsorption Interactions in Metal-Organic Frameworks using X-ray Spectroscopy" Drisdell. W. S.; Poloni, R.; McDonald, T. M.; Long, J. R.; Smit, B.; Neaton, J. B.; Prendergast, D.; Kortright, J. B. J. Am. Chem. Soc. 2013, 135, 18183-18190.

(183) view "Magnetic Blocking at 10 K and a Dipolar-Mediated Avalanche in Salts of the Bis(η8-cyclooctatetraenide) Complex [Er(COT)2]-" Meihaus, K. R.; Long, J. R. J. Am. Chem. Soc. 2013, 135, 17952-17957.

(182) view "Electrodeposited Cobalt-Sulfide Catalyst for Electrochemical and Photoelectrochemical Hydrogen Generation from Water" Sun, Y.; Liu, C.; Grauer, D. C.; Yano, J.; Long, J. R.; Yang, P.; Chang, C. J. J. Am. Chem. Soc. 2013, 135, 17699-17702.

(181) view "Mossbauer Spectroscopy as a Probe of Magnetization Dynamics in the Linear Iron(I) and Iron(II) Complexes [Fe(C(SiMe3)3)2]1-/0" Zadrozny, J. M.; Xiao, D. J.; Long, J. R.; Atanasov, M.; Neese, F.; Grandjean, F.; Long, G. J. Inorg. Chem. 2013, 52, 13123-13133.

(180) view "Tristability in a Light Actuated Single-Molecule Magnet" Feng, X.; Mathoniere, C.; Jeon, I.; Rouzieres, M.; Ozarowski, A.; Aubrey, M. L.; Gonzalez, M. I.; Clerac, R.; Long, J. R. J. Am. Chem. Soc. 2013, 135, 15880-15884.

(179) view "Ex Situ NMR Relaxometry of Metal–Organic Frameworks for Rapid Surface-Area Screenings" Chen, J. J.; Kong, X.; Sumida, K.; Manumpil, M. A.; Long, J. R.; Reimer, J. A. Angew. Chem. Int. Ed. 2013, 52, 12043-12046.

(178) view "CO2/N2 Separations with Mixed-Matrix Membranes Containing Mg2(dobdc) Nanocrystals" Bae, T.; Long, J. R. Energy Environ. Sci. 2013, 6, 3565-3569.

(177) view "Catalytic Proton Reduction with Transition Metal Complexes of the Redox-Active Ligand bpy2PYMe" Nippe, M.; Khnayzer, R. S.; Panetier, J. A.; Zee, D. Z.; Olaiya, B. S.; Head-Gordon, M.; Chang, C. J.; Castellano, F. N.; Long, J. R. Chem. Sci. 2013, 4, 3934-3945.

(176) view "Single-Ion Magnetic Anisotropy and Isotropic Magnetic Couplings in the Metal-Organic Framework Fe2(dobdc)" Maurice, R.; Verma, P.; Zadrozny, J. M.; Luo, S.; Borycz, J.; Long, J. R.; Truhlar, D. G.; Gagliardi, L. Inorg. Chem. 2013, 52, 9379-9389.

(175) view "Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels" Herm, Z. R.; Wiers, B. M.; Mason, J. A.; van Baten, J. M.; Hudson, M. R.; Zajdel, P.; Brown, C. M.; Masciocchi, N.; Krishna, R.; Long, J. R. Science 2013, 340, 960-964.

(174) view "Magnetic Blocking in a Linear Iron(I) Complex" Zadrozny, J. M.; Xiao, D. J.; Atanasov, M.; Long, G. J.; Grandjean, F.; Neese, F.; Long, J. R. Nature Chem. 2013, 5, 577-581.

(173) view "Slow Magnetic Relaxation in the Tetrahedral Cobalt(II) Complexes [Co(EPh)4]2- (E=O, S, Se)" Zadrozny, J. M.; Telser, J.; Long, J. R. Polyhedron 2013, 64, 209-217.

(172) view "The Mechanism of Carbon Dioxide Adsorption in an Alkylamine-Functionalized Metal-Organic Framework" Planas, N.; Dzubak, A. L.; Poloni, R.; Lin, L. C.; McManus, A.; McDonald, T. M.; Neaton, J. B.; Long, J. R.; Smit, B.; Gagliardi, L. J. Am. Chem. Soc. 2013, 135, 7402-7405.

(171) view "Stable Dye-Sensitized Solar Cell Electrolytes Based on Cobalt(II)/(III) Complexes of a Hexadentate Pyridyl Ligand" Kashif, M. K.; Nippe, M.; Duffy, N. W.; Forsyth, C. M.; Chang, C. J.; Long, J. R.; Spiccia, L.; Bach, U. Angew. Chem. Int. Ed. 2013, 52, 5527-5531.

(170) view "Understanding CO2 Dynamics in Metal–Organic Frameworks with Open Metal Sites" Lin, L.-C.; Kim, J.; Kong, X.; Scott, E.; McDonald, T. M.; Long, J. R.; Reimer, J. A.; Smit, B. Angew. Chem. Int. Ed. 2013, 52, 4410-4413.

(169) view "Ionic Conductivity in the Metal–Organic Framework UiO-66 by Dehydration and Insertion of Lithium tert-Butoxide" Ameloot, R.; Aubrey, M.; Wiers, B. M.; Gomora-Figueroa, A. P.; Patel, S. N.; Balsara, N. P.; Long, J. R. Chem. Eur. J. 2013, 19, 5533-5536.

(168) view "Selective Adsorption of Ethylene over Ethane and Propylene over Propane in the Metal-Organic Frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn)" Geier, S. J.; Mason, J. A.; Bloch, E.D.; Queen, W. L.; Hudson, M. R.; Brown, C. M.; Long, J. R. Chem. Sci. 2013, 4, 2054-2061.

(167) view "A Mechanistic Study of Proton Reduction Catalyzed by a Pentapyridine Cobalt Complex: Evidence for Involvement of an Anation-Based Pathway" King, A. E.; Surendranath, Y.; Piro, N. A.; Bigi, J. P.; Long, J. R.; Chang, C. J. Chem. Sci. 2013, 4, 1578-1587.

(166) view "Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of M-BTT Metal-Organic Frameworks" Sumida, K.; Stuck, D.; Mino, L.; Chai, J.-D.; Bloch, E. D.; Zavorotynska, O.; Murray, L. J.; Dinca, M.; Chavan, S.; Bordiga, S.; Head-Gordon, M.; Long, J. R. J. Am. Chem. Soc. 2013, 135, 1083-1091.

(165) view "A Theoretical Analysis of Chemical Bonding, Vibronic Coupling, and Magnetic Anisotropy in Linear Iron(II) Complexes with Single-Molecule Magnet Behavior" Atanasov, M.; Zadrozny; J. M.; Long, J. R.; Neese, F. Chem. Sci. 2013, 4, 139-156.

(164) view "Slow Magnetization Dynamics in a Series of Two-Coordinate Iron(II) Complexes" Zadrozny, J. M.; Atanasov, M.; Bryan, A. M.; Lin, C.-Y.; Rekken, B. D.; Power, P. P.; Neese, F.; Long, J. R. Chem. Sci . 2013, 4, 125-138.

(163) view "Evaluation of Cation-Exchanged Zeolite Adsorbents for Post-Combustion Carbon Dioxide Capture" Bae, T.-H.; Hudson, M. R.; Mason, J. A.; Queen, W. L.; Dutton, J. J.; Sumida, K.; Micklash, K. J.; Kaye, S. S.; Brown, C. M.; Long, J. R. Energy Environ. Sci. 2013, 6, 128-138.

(162) view "Complexes of Earth-Abundant Metals for Catalytic Electrochemical Hydrogen Generation under Aqueous Conditions" Thoi, V. S.; Sun, Y.; Long, J. R.; Chang, C. J. Chem. Soc. Rev. 2013, 42, 2388-2400.

(161) view "Photocatalytic Generation of Hydrogen from Water Using a Cobalt Pentapyridine Complex in Combination with Molecular and Semiconductor Nanowire Photosensitizers" Sun, Y.; Sun, J.; Long, J. R.; Yang, P.; Chang, C. J. Chem. Sci. 2013, 4, 118-124 .

(160) view "Exchange Coupling and Magnetic Blocking in Bipyrimidyl Radical-Bridged Dilanthanide Complexes" Demir, S.; Zadrozny; J. M.; Nippe, M.; Long, J. R. J. Am. Chem. Soc. 2012, 134, 18546-18549.

(159) view "A New Direction in Dye-Sensitized Solar Cells Redox Mediator Development: In Situ Fine-Tuning of the Cobalt(II)/(III) Redox Potential through Lewis Base Interactions" Kashif, M. K.; Axelson, J. C.; Duffy, N. W.; Forsyth, C. M.; Chang, C. J.; Long, J. R.; Spiccia, L.; Bach, U. J. Am. Chem. Soc. 2012, 134, 16646-16653.

(158) view "CO2 Dynamics in a Metal-Organic Framework with Open Metal Sites" Kong, X.; Scott, E.; Ding, W.; Mason, J. A.; Long, J. R.; Reimer, J. A. J. Am. Chem. Soc. 2012, 134, 14341-14344.

(157) view "Slow Magnetic Relaxation in Homoleptic Trispyrazolylborate Complexes of Neodymium(III) and Uranium(III)" Rinehart, J. D.; Long, J. R. Dalton Trans. 2012, 41, 13572-13574 .

(156) view "Electrochemical Generation of Hydrogen from Acetic Acid Using a Molecular Molybdenum–Oxo Catalyst" Thoi, V. S.; Karunadasa, H. I.; Surendranath, Y.; Long, J. R.; Chang, C. J. Energy Environ. Sci. 2012, 5, 7762-7770 .

(155) view "Slow Magnetic Relaxation Induced by a Large Transverse Zero-Field Splitting in a MnIIReIV(CN)2 Single-Chain Magnet" Feng, X; Liu, J.; Harris, T. D.; Hill, S.; Long, J. R. J. Am. Chem. Soc. 2012, 134, 7521-7529 .

(154) view "Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal-Organic Framework mmen-Mg2(dobpdc)" McDonald, T. M.; Lee, W. R.; Mason, J. A.; Wiers, B. M.; Hong, C. S.; Long, J. R. J. Am. Chem. Soc. 2012, 134, 7056-7065 .

(153) view "Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites" Bloch, E. D.; Queen, W. L.; Krishna, R.; Zadrozny, J. M.; Brown, C. M.; Long, J. R. Science 2012, 335, 1606-1610 .

(152) view "Computational and Experimental Study of the Mechanism of Hydrogen Generation from Water by a Molecular Molybdenum-Oxo Electrocatalyst" Sundstrom, E. J.; Yang, X.; Thoi, V. S.; Karunadasa, H. I.; Chang, C. J.; Long, J. R.; Head-Gordon, M. J. Am. Chem. Soc. 2012, 134, 5233-5242 .

(151) view "Hydrogen Adsorption in the Metal–Organic Frameworks Fe2(dobdc) and Fe2(O2)(dobdc) " Queen, W. L.; Bloch, E. B.; Brown, C. M.; Hudson, M. R.; Mason, J. A.; Murray, L. J.; Ramirez-Cuesta, A. J.; Peterson, V. K.; Long, J. R. Dalton Trans. 2012, 41, 4180-4187 .

(150) view "A Molecular MoS2 Edge Site Mimic for Catalytic Hydrogen Generation" Karunadasa, H. I.; Montalvo, E.; Sun, Y.; Majda, M.; Long, J. R.; Chang, C. J. Science 2012, 335, 698-702.

(149) view "Carbon Dioxide Capture in Metal-Organic Frameworks" Sumida, K.; Rogow, D. L.; Mason, J. A.; McDonald, T. M.; Bloch, E. D.; Herm, Z. R.; Bae, T.-H.; Long, J. R. Chem. Rev. 2012, 112, 724-781.

(148) view "Slow Magnetic Relaxation in a Pseudotetrahedral Cobalt(II) Complex with Easy-Plane Anisotropy" Zadrozny, J. M.; Liu, J.; Piro, N. A.; Chang, C. J.; Hill, S.; Long, J. R. Chem. Commun. 2012, 48, 3927-3929.

(147) view "CO2/CH4, CH4/H2 and CO2/CH4/H2 Separations at High Pressures Using Mg2(dobdc) " Herm, Z. R.; Krishna, R.; Long, J. R. Microporous Mesoporous. Mater. 2012, 151, 481-487.

(146) view "Synthesis, Structure, and Magnetism of an f Element Nitrosyl Complex, (C5Me4H)3UNO" Siladke, N. A.; Meihaus, K. R.; Ziller, J. W.; Fang, M.; Furche, F.; Long, J. R.; Evans, W. J. J. Am. Chem. Soc. 2012, 134, 1243-1249.

(145) view "Slow Magnetic Relaxation at Zero Field in the Tetrahedral Complex [Co(SPh)4]2-" Zadrozny, J. M.; Long, J. R. J. Am. Chem. Soc. 2011, 133, 20732-20734.

(144) view "Structural and Electronic Study of an Amorphous MoS3 Hydrogen-Generation Catalyst on a Quantum-Controlled Photosensitizer" Tang, M. L.; Grauer, D. C.; Lassalle-Kaiser, B.; Yachandra, V. K.; Amirav, L.; Long, J. R.; Yano, J.; Alivisatos, A. P. Angew. Chem. Int. Ed. 2011, 50, 10203-10207.

(143) view "Exploiting Single-Ion Anisotropy in the Design of f-Element Single-Molecule Magnets" Rinehart, J. D.; Long, J. R. Chem. Sci. 2011, 2, 2078-2085.

(142) view "A Solid Lithium Electrolyte via Addition of Lithium Isopropoxide to a Metal-Organic Framework with Open Metal Sites" Wiers, B. M.; Foo, M.-L.; Balsara, N. P.; Long, J. R. J. Am. Chem. Soc. 2011, 133, 14522-14525.

(141) view "Selective Binding of O2 over N2 in a Redox-Active Metal-Organic Framework with Open Iron(II) Coordination Sites" Bloch, E. D.; Murray, L. M.; Queen, W. L.; Chavan, S.; Maximoff, S. N.; Bigi, J. P.; Krishna, R.; Peterson, V. K.; Grandjean, F.; Long, G. J.; Smit, B.; Bordiga, S.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2011, 133, 14814-14822.

(140) view "A N23- Radical-Bridged Terbium Complex Exhibiting Magnetic Hysteresis at 14 K" Rinehart, J. D.; Fang, M.; Evans, W. J.; Long, J. R. J. Am. Chem. Soc. 2011, 133, 14236-14239.

(139) view "Dilution-Induced Slow Magnetic Relaxation and Anomalous Hysteresis in Trigonal Prismatic Dysprosium(III) and Uranium(III) Complexes" Meihaus, K. R.; Rinehart, J. D.; Long, J. R. Inorg. Chem. 2011, 50, 8484-8489.

(138) view "Enhanced Carbon Dioxide Capture upon Incorporation of N,N'-Dimethylethylenediamine in the Metal-Organic Framework CuBTTri" McDonald, T. M.; D'Alessandro, D. M.; Krishna, R.; Long, J. R. Chem. Sci. 2011, 2, 2022-2028.

(137) view "Evaluating Metal-Organic Frameworks for Post-Combustion Carbon Dioxide Capture via Temperature Swing Adsorption" Mason, J. A.; Sumida, K.; Herm, Z. R.; Krishna, R.; Long, J. R. Energy Environ. Sci. 2011, 4, 3030-3040.

(136) view "Screening Metal-Organic Frameworks by Analysis of Transient Breakthrough of Gas Mixtures in a Fixed Bed Adsorber" Krishna, R.; Long, J. R. J. Phys. Chem. C. 2011, 115, 12941-12950.

(135) view "Molecular Cobalt Pentapyridine Catalysts for Generating Hydrogen from Water" Sun, Y.; Bigi, J. P.; Piro, N. A.; Tang, M. L.; Long, J. R.; Chang, C. J. J. Am. Chem. Soc. 2011, 133, 9212-9215.

(134) view "Influence of Structure on Exchange Strength and Relaxation Barrier in a Series of FeIIReIV(CN)2 Single-Chain Magnets" Feng, X.; Harris, T. D.; Long, J. R. Chem. Sci. 2011, 2, 1688-1694

(133) view "Strong Exchange and Magnetic Blocking in N23- Radical-Bridged Lanthanide Complexes" Rinehart, J. D.; Fang, M.; Evans, W. J.; Long, J. R. Nat. Chem. 2011, 3, 538-542.

(132) view "High Thermal and Chemical Stability in Pyrazolate-Bridged Metal-Organic Frameworks with Exposed Metal Sites" Colombo, V.; Galli, S.; Choi, H. J.; Han, G. D.; Maspero, A.; Palmisano, G.; Masciocchi, N.; Long, J. R. Chem. Sci. 2011,2, 1311-1319.

(131) view "Metal-Organic Frameworks as Adsorbents for Hydrogen Purification and Precombustion Carbon Dioxide Capture" Herm, Z. R.; Swisher, J. A.; Smit, B.; Krishna, R; Long, J. R. J. Am. Chem. Soc. 2011, 133, 5664-5667.

(130) view "Neutron Scattering and Spectroscopic Studies of Hydrogen Adsorption in Cr3(BTC)2 - A Metal-Organic Framework with Exposed Cr2+ Sites" Sumida, K.; Her, J. H.; Dincă, M.; Murray, L. J.; Schloss, J. M.; Pierce, C. J.; Thompson, B. A.; FitzGerald, S. A.; Brown, C. M.; Long, J. R. J. Phys. Chem. C 2011, 115, 8414-8421.

(129) view "Microporous Magnets" Dechambenoit, P.; Long, J. R. Chem. Soc. Rev. 2011, 40, 3249-3265.

(128) view "A Cyano-Bridged FeIIReIV(CN)2 Cluster Incorporating Two High-Magnetic Anisotropy Building Units" Harris, T. D.; Soo, H.; Chang, C. J.; Long, J. R. Inorg. Chim. Acta. 2011, 369, 91-96.

(127) view "Record Ferromagnetic Exchange through Cyanide and Elucidation of the Magnetic Phase Diagram for a CuIIReIV(CN)2 Chain Compound" Harris, T. D.; Coulon, C.; Clérac, R.; Long, J. R. J. Am. Chem. Soc. 2011, 133, 123-130.

(126) view "Hydrogen Storage Properties and Neutron Scattering Studies of Mg2(dobdc) - A Metal-Organic Framework with Open Mg2+ Adsorption Sites" Sumida, K.; Brown, C. M.; Herm, Z. R.; Chavan, S.; Bordiga, S.; Long, J. R. Chem. Commun.2011, 47, 1157-1159.

(125) view "Slow Magnetic Relaxation in a Family of Trigonal Pyramidal Iron(II) Pyrrolide Complexes" Harman, W. H.; Harris, T. D.; Freedman, D. E.; Fong, H.; Chang, A.; Rinehart, J. D.; Ozarowski, A.; Sougrati, M. T.; Grandjean, F.; Long, G. J.; Long, J. R.; Chang, C. J. J. Am. Chem. Soc. 2010, 132, 18115-18126.

(124) view "First-Row Transition Metal Complexes of the Strongly Donating Pentadentate Ligand PY4Im" Smith, J. M.; Long, J. R. Inorg. Chem. 2010, 49, 11223-11230.

(123) view "A Novel Microporous MOF with the Capability of Selective Adsorption of Xylenes" Jin, Z.; Zhao, H.; Zhao, X.; Fang, Q.; Long, J. R.; Zhu, G. Chem. Commun. 2010, 46, 8612-8614.

(122) view "Metal Insertion in a Microporous Metal-Organic Framework Lined with 2,2'-Bipyridine" Bloch, E. D.; Britt, D.; Doonan, C. J.; Uribe-Romo, F. J.; Furukawa, H.; Long, J. R.; Yaghi, O. M. J. Am. Chem. Soc. 2010, 132, 14382-14384.

(121) view "Multistep N2 Breathing in the Metal-Organic Framework Co(1,4-benzenedipyrazolate)" Salles, F.; Maurin, G.; Serre, C.; Llewellyn, P. L.; Knofel, C.; Choi, H. J.; Filinchuk, Y.; Oliviero, L.; Vimont, A.; Long, J. R.; Ferey, G. J. Am. Chem. Soc. 2010, 132, 13782-13788.

(120) view "Slow Magnetic Relaxation and Charge-Transfer in Cyano-Bridged Coordination Clusters Incorporating [Re(CN)7]3-/4-" Zadrozny, J. M.; Freedman, D. E.; Jenkins, D. M.; Harris, T. D.; Iavarone, A. T.; Mathoniere, C.; Clérac, R.; Long, J. R.Inorg. Chem. 2010, 49, 8886-8896.

(119) view "Carbon Dioxide Capture: Prospects for New Materials" D'Alessandro, D. M.; Smit, B.; Long, J. R. Angew. Chem., Int. Ed. 2010, 49, 6058-6082.

(118) view "Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal-Organic Framework" Kobayashi, Y.; Jacobs, B.; Allendorf, M. D.; Long, J. R. Chem. Mater. 2010, 22, 4120-4122.

(117) view "Highly-Selective and Reversible O2 Binding in Cr3(1,3,5-benzenetricarboxylate)2" Murray, L. J.; Dincă, M.; Yano, J.; Chavan, S.; Bordiga, S.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2010, 132, 7856-7857.

(116) view "Observation of a Secondary Slow Relaxation Process for the Field-Induced Single-Molecule Magnet U(H2BPz2)3" Rinehart, J. D.; Meihaus, K. R.; Long, J. R. J. Am. Chem. Soc. 2010, 132, 7572-7573.

(115) view "Enhancing the Magnetic Anisotropy of Cyano-Ligated Chromium(II) and Chromium(III) Complexes via Heavy Halide Ligand Effects" Karunadasa, H. I.; Arquero, K. D.; Berben, L. A.; Long, J. R. Inorg. Chem. 2010, 49, 4738-4740.

(114) view "Synthesis and Structural Flexibility of a Series of Cu(II) Azolate-Based Metal-Organic Frameworks" Sumida, K.; Foo, M. L; Horike, S.; Long, J. R. Eur. J. Inorg. Chem. 2010, 3739-3744.

(113) view "Hydrogen Storage and Carbon Dioxide Capture in an Iron-Based Sodalite-Type Metal-Organic Framework (Fe-BTT) Discovered via High-Throughput Methods" Sumida, K.; Horike, S.; Kaye, S. S.; Herm, Z. R.; Queen, W. L; Brown, C. M.; Grandjean, F.; Long, G. J.; Dailly, A.; Long, J. R. Chem. Sci. 2010, 1, 184-191.

(112) view "A Molecular Molybdenum-Oxo Catalyst for Generating Hydrogen from Water" Karunadasa, H. I.; Chang, C. J.; Long, J. R. Nature 2010, 464, 1329-1333.

(111) view "Selective Gas Adsorption in the Flexible Metal-Organic Frameworks Cu(BDTri)L (L = DMF, DEF)" Demessence, A.; Long, J. R. Chem. Eur. J. 2010, 16, 5902-5908.

(110) view "High-Spin Ground States via Electron Delocalization in Mixed-Valence Imidazolate-Bridged Divanadium Complexes" Bechlars, B.; D'Alessandro, D. M.; Jenkins, D. J.; Iavarone, A. T.; Glover, S. D.; Kubiak, C. P.; Long, J. R. Nat. Chem. 2010, 2, 362-368.

(109) view "Tetranuclear Uranium Clusters by Reductive Cleavage of 3,5-Dimethylpyrazolate" Rinehart, J. D.; Kozimor, S. A.; Long, J. R. Angew. Chem. Int. Ed. 2010, 49, 2560-2564.

(108) view "[ReCl4(CN)2]2-: A High Magnetic Anisotropy Building Unit Giving Rise to the Single-Chain Magnets (DMF)4MReCl4(CN)2(M = Mn, Fe, Co, Ni)" Harris, T. D.; Bennett, M. V.; Clérac, R.; Long, J. R. J. Am. Chem. Soc. 2010, 132, 3980-3988.

(107) view "Slow Magnetic Relaxation in a High-Spin Iron(II) Complex" Freedman, D. E.; Harman, W. H.; Harris, T. D.; Long, G. J.; Chang, C. J.; Long, J. R. J. Am. Chem. Soc. 2010, 132, 1224-1225.

(106) view "Hydrogen Storage in Water-Stable Metal-Organic Frameworks Incorporating 1,3- and 1,4-Benzenedipyrazolate" Choi, H. J.; Dincă, M.; Dailly, A.; Long, J. R. Energy Environ. Sci. 2010, 3, 117-123.

(105) view "Synthesis and Hydrogen Storage Properties of Be12(OH)12(1,3,5-benzenetribenzoate)4" Sumida, K.; Hill, M. R.; Horike, S.; Dailly, A.; Long, J. R. J. Am. Chem. Soc. 2009, 131, 15120-15121.

(104) view "Slow Magnetic Relaxation in a Trigonal Prismatic Uranium(III) Complex" Rinehart, J. D.; Long, J. R. J. Am. Chem. Soc. 2009, 131, 12558-12559.

(103) view "Synthesis, Structure, and Magnetic Characterization of a C3-Symmetric Mn(III)3Cr(III) Assembly: Molecular Recognition Between a Trinuclear Mn(III) Triplesalen Complex and a fac-Tricyano Cr(III) Complex" Freiherr von Richthofen, C.-G.; Stammler, A.; Bogge, H.; DeGroot, M. W.; Long, J. R.; Glaser, T. Inorg. Chem. 2009, 48, 10165-10176.

(102) view "Strong Magnetic Exchange Coupling in the Cyano-Bridged Coordination Clusters [(PY5Me2)4V4M(CN)6]5+ (M = Cr, Mo)" Freedman, D. E.; Jenkins, D. M.; Long, J. R., Chem. Commun. 2009, 4829-4831.

(101) view "Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal-Organic Framework Functionalized with Ethylenediamine" Demessence, A.; D'Alessandro, D. M.; Foo, M. L.; Long, J. R., J. Am. Chem. Soc. 2009, 131, 8784-8786.

(100) view "Tuning Molecule-Mediated Spin Coupling in Bottom-Up Fabricated Vanadium-TCNE Nanostructures" Wegner, D.; Yamachika, R.; Zhang, X.; Wang, Y.; Baruah, T.; Pederson, M. R.; Bartlett, B. M.; Long, J. R.; Crommie, M. F., Phys. Rev. Lett. 2009, 103, 087205.

(99) view "Synthesis and Characterization of Ruthenium and Iron-Ruthenium Prussian Blue Analogues" Behera, J.; D'Alessandro, D. M.; Soheilnia, N.; Long, J. R., Chem. Mater. 2009, 21, 1922-1926.

(98) view "Hydrogen Storage in Metal-Organic Frameworks" Murray, L. J.; Dincă, M.; Long, J. R. Chem. Soc. Rev. 2009, 38, 1294-1314.

(97) view "The Pervasive Chemistry of Metal-Organic Frameworks" Long, J. R.; Yaghi, O. M. Chem. Soc. Rev. 2009, 38, 1213-1214.

(96) view "Surface Charge of Polyoxometalates Modulates Polymerization of the Scrapie Prion Protein" Wille, H.; Shanmugan, M.; Murugesu, M.; Ollesch, J.; Stubbs, G.; Long, J. R.; Safar, J. G.; Prusiner, S. B., Proc. Nat. Acad. Sci. 2009, 106, 3740-3745.

(95) view "Local Electronic Properties of Titanocene Chloride Dimer Molecules on a Metal Surface" Yamachika, R.; Lu, X.; Wegner, D.; Wang, Y.; Wachowiak, A.; Grobis, M.; Beltran, L. M. C..; Long, J. R.; Pederson, M.; Crommie, M. F. J. Phys. Chem. C 2009, 113, 677-680.

(94) view "Synthesis and Redox-Induced Structural Isomerization of the Pentagonal Bipyramidal Complexes [W(CN)5(CO)2]3-/2-" Karunadasa, H. I.; Long. J. R. Angew. Chem. Int. Ed. 2009, 48, 738-741.

(93) view "Magnetic Exchange Coupling in Actinide-Containing Molecules" Rinehart, J. D.; Harris, T. D.; Kozimor, S. A.; Bartlett, B. M.; Long. J. R. Inorg. Chem. 2009, 48, 3382-3395.

(92) view "Structure and Charge Control in Metal-Organic Frameworks Based on the Tetrahedral Ligand Tetrakis(4-tetrazolylphenyl)methane" Dincă, M.; Dailly, A.; Long, J. R. Chem. Eur. J. 2008, 14, 10280-10285.

(91) view "Generation and O2 Adsorption Studies of the Microporous Magnets CsNi[Cr(CN)6] (Tc = 75 K) and Cr3[Cr(CN)6]2·6H2O (TN = 219 K)" Kaye, S. S.; Choi, H. J.; Long, J. R. J. Am. Chem. Soc. 2008, 130, 16921-16925.

(90) view "Broadly Hysteretic H2 Adsorption in the Microporous Metal-Organic Framework Co(1,4-benzenedipyrazolate)" Choi, H. J.; Dincă, M.; Long, J. R. J. Am. Chem. Soc. 2008, 130, 7848-7850.

(89) view "Hydrogen Storage in Microporous Metal-Organic Frameworks with Exposed Metal Sites" Dincă, M.; Long, J. R. Angew. Chem. Int. Ed. 2008, 47, 6766-6779.

(88) view "Ferromagnetic Exchange Coupling in the Linear, Chloride-Bridged Cluster (cyclam)CoII[(μ-Cl)UIV(Me2Pz)4]2" Rinehart, J. D.; Bartlett, B. M.; Kozimor, S. A.; Long, J. R. Inorg. Chim. Acta. 2008, 361, 3534-3538 .

(87) view "Size-Selective Lewis-Acid Catalysis in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites" Horike, S.; Dincă, M.; Tamaki, K.; Long, J. R. J. Am. Chem. Soc. 2008, 130, 5854-5855.

(86) view "Synthesis and Characterization of the Cubic Coordination Cluster [CoIII6CoII2(IBT)12]14- (H3IBT = 4,5-bis(tetrazol-5-yl)imidazole)" Dincă, M.; Harris, T. D.; Iavarone, A. T.; Long, J. R. J. Mol. Struct. 2008, 890, 139-143.

(85) view "A Redox-Switchable Single-Molecule Magnet Incorporating [Re(CN)7]3-" Freedman, D. E.; Jenkins, D. M.; Iavarone, A. T.; Long, J. R. J. Am. Chem. Soc. 2008, 130, 2884-2885.

(84) view "Matrix Isolation Chemistry in a Porous Metal-Organic Framework: Photochemical Substitutions of N2 and H2 in Zn4O[(η6-1,4-benzenedicarboxylate)Cr(CO)3]3" Kaye, S. S.; Long, J. R. J. Am. Chem. Soc. 2008, 130, 806-807.

(83) view "Single-Molecule Charge Transfer and Bonding at an Organic/Inorganic Interface: Tetracyanoethylene on Noble Metals" Wegner, D.; Yamachika, R.; Wang, Y.; Brar, V. W.; Bartlett, B. M.; Long, J. R.; Crommie, M. F. Nano Lett. 2008, 8, 131-135.

(82) view "Expanded Sodalite-Type Metal-Organic Frameworks: Increased Stability and H2 Adsorption through Ligand-Directed Catenation" Dincă, M.; Dailly, A.; Tsay, C.; Long, J. R. Inorg. Chem. 2008, 47, 11-13.

(81) view "Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5) " Kaye, S. S.; Dailly, A.; Yaghi, O. M.; Long, J. R. J. Am. Chem. Soc. 2007, 129, 14176-14177.

(80) view "Hydrogen Adsorption in Dehydrated Variants of the Cyano-Bridged Framework Compounds A2Zn3[Fe(CN)6]2·xH2O (A = H, Li, Na, K, Rb)" Kaye, S. S.; Long, J. R. Chem. Commun. 2007, 4486-4488.

(79) view "High-Spin Ni3Fe2(CN)6 and Cu3Cr2(CN)6 Clusters Based on a Trigonal Bipyramidal Geometry" Bartlett, B. M.; Harris, T. D.; DeGroot, M. W.; Long, J. R. Z. Anorg. Allg. Chem. 2007, 2380-2385.

(78) view "High-Enthalpy Hydrogen Adsorption in Cation-Exchanged Variants of the Microporous Metal-Organic Framework Mn3[(Mn4Cl)3(BTT)8(CH3OH)10]2" Dincă, M.; Long, J. R. J. Am. Chem. Soc. 2007, 129, 11172-11176.

(77) view "Magnetic Exchange Coupling in Chloride-Bridged 5f-3d Heterobimetallic Complexes Generated via Insertion into a Uranium(IV) Dimethylpyrazolate Dimer" Kozimor, S. A.; Bartlett, B. M.; Rinehart, J. D.; Long, J. R. J. Am. Chem. Soc. 2007, 129, 10672-10674.

(76) view "Synthesis and Characterization of the Face-Centered Cubic Clusters [(Me3tacn)8M8Pt6(CN)24]12+ (M = Cr, Mo)" Beltran, L. M. C.; Sokol, J. J.; Long, J. R. J. Clust. Sci. 2007, 18, 575-596.

(75) view "Synthesis and Ligand Exchange Kinetics of the Solvated Trigonal Prismatic Clusters [W6CCl12L6]2+ (L = DMF, py)" Welch, E. J.; Long, J. R. Angew. Chem. Int. Ed. 2007, 46, 3494-3496.

(74) view "Observation of CuII-H2 Interactions in a Fully-Desolvated, Sodalite-Type Metal-Organic Framework" Dincă, M.; Han, W. S.; Liu, Y.; Dailly, A.; Brown, C. M.; Long, J. R. Angew. Chem. Int. Ed. 2007, 46, 1419-1422.

(73) view "Linkage Isomerism in a Face-Centered Cubic Cu6Cr8(CN)24 Cluster with an S = 15 Ground State" Harris, T. D.; Long, J. R. Chem. Commun. 2007, 1360-1362.

(72) view "Syntheses, Structures, and Magnetic Properties of the Face-Centered Cubic Clusters [Tp8(H2O)12M6Fe8(CN)24]4+ (M = Co, Ni)" Jiang, L.; Choi, H. J.; Feng, X.-L; Lu, T.-B.; Long, J. R. Inorg. Chem. 2007, 46, 2181-2186.

(71) view "The Role of Vacancies in the Hydrogen Storage Properties of Prussian Blue Analogues" Kaye, S. S.; Long, J. R. Catal. Today 2007, 120, 311-316.

(70) view "Determination of 77Se-77Se and 77Se-13C J-Coupling Parameters for the Clusters [Re5OsSe8(CN)6]3- and [Re4Os2Se8(CN)6]2-" Ramaswamy, K.; Tulsky E. G.; Long, J. R.; Kao, J. L.-F.; Hayes S. E. Inorg. Chem. 2007, 46, 1177-1186.

(69) view "Hydrogen Storage in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites" Dincă, M.; Dailly, A.; Liu, Y.; Brown, C. M.; Neumann, D. A.; Long, J. R. J. Am. Chem. Soc. 2006, 128, 16876-16883.

(68) view "Signatures of Molecular Magnetism in Single-Molecule Transport Spectroscopy" Jo, M.-H.; Grose, J. E.; Baheti, K.;Deshmukh, M. M.; Sokol, J. J.; Rumberger, E. M.; Hendrickson, D. N.; Long, J. R.; Park, H.; Ralph, D. C. Nano Lett. 2006, 6, 2014-2020.

(67) view "Neutron Diffraction and Neutron Vibrational Spectroscopy Studies of Hydrogen Adsorption in the Prussian Blue Analogue Cu3[Co(CN)6]2" Hartman, M. R.; Peterson, V. K.; Liu, Y.; Kaye, S. S.; Long, J. R. Chem. Mater. 2006, 18, 3221-3224.

(66) view "Angle-Dependent Electronic Coupling in 4,4'-Bipyridine-Bridged Ru3 Triangle and Ru4 Square Complexes" Berben, L. A.; Faia, M. C.; Crawford N. R. M.; Long, J. R. Inorg. Chem. 2006, 45, 6378-6386.

(65) view "Microporous Metal-Organic Frameworks Incorporating 1,4-Benzeneditetrazolate: Syntheses, Structures, and Hydrogen Storage Properties" Dincă, M.; Yu, A. F.; Long, J. R. J. Am. Chem. Soc. 2006, 128, 8904-8913.

(64) view "Symmetry-Based Magnetic Anisotropy in the Trigonal Bipyramidal Cluster [Tp2(Me3tacn)3Cu3Fe2(CN)6]4+" Wang, C.-F; Zuo, J.-L.; Bartlett, B. M.; Song, Y.; Long, J. R.; You, X.-Z. J. Am. Chem. Soc. 2006, 128, 7162-7163.

(63) view "Symmetry-Breaking Substitutions of [Re(CN)8]3- into the Centered, Face-Capped Octahedral Clusters (CH3OH)24M9M'6(CN)48 (M = Mn, Co; M' = Mo, W)" Freedman, D. E.; Bennett, M. V.; Long, J. R. Dalton Trans. 2006, 2829-2834.

(62) view "Synthesis and Characterization of Prussian Blue Analogues Incorporating the Edge-Bridged Octahedral [Zr6BCl12]2+ Cluster Core" Beauvais L. G.; Long, J. R. Inorg. Chem. 2006, 45, 236-243.

(61) view "Selective Precipitation of Prions by Polyoxometalate Complexes" Lee, I. S.; Long, J. R.; Prusiner, S. B.; Safar, J. G. J. Am. Chem. Soc. 2005, 127, 13802-13803.

(60) view "Homoleptic Trimethysilylacetylide Complexes of Chromium(III), Iron(II), and Cobalt(III): Syntheses, Structures, andLigand Field Parameters" Berben, L. A.; Long, J. R. Inorg. Chem. 2005, 44, 8459-8468.

(59) view "Strong H2 Binding and Selective Gas Adsorption within the Microporous Coordination Solid Mg3(O2C-C10H6-CO2)3"Dincă, M.; Long, J. R. J. Am. Chem. Soc. 2005, 127, 9376-9377.

(58) view "Hydrogen Storage in the Dehydrated Prussian Blue Analogues M3[Co(CN)6]2 (M = Mn, Fe, Co, Ni, Cu, Zn)" Kaye, S. S.; Long, J. R. J. Am. Chem. Soc. 2005, 127, 6506-6507.

(57) view "Synthesis and Characterization of the Nitrogen-Centered Trigonal Prismatic Clusters [W6NCl18]n-;(n = 1, 2, 3)" Welch, E. J.; Yu, C. L.; Crawford, N. R. M.; Long, J. R. Angew. Chem., Int. Ed. 2005, 44, 2549-2553.

(56) view "Directed Assembly of Metal-Cyanide Cluster Magnets" Beltran, L. M. C.; Long, J. R. Acc. Chem. Res. 2005, 38, 325-334.

(55) view "Atomlike Building Units of Adjustable Character: Solid-State and Solution Routes to Manipulating Hexanuclear Transition Metal Chalcohalide Clusters" Welch, E. J.; Long, J. R. Prog. Inorg. Chem. 2005, 54, 1-45.

(54) view "Synthesis and Magnetic Behavior of the Tetrahedral Cage Complex [(cyclen)4V4(CN)6]6+" Lee, I. S.; Long, J. R.Dalton Trans. 2004, 3434-3436.

(53) view "[(Tp)8(H2O)6CuII6FeIII8(CN)24]4+: A Cyano-Bridged Face-Centered Cubic Cluster with Single-Molecule-Magnet Behavior" Wang, S.; Zou, J.-L.; Zhou, H.-C.; Choi, H. J.; Ke, Y.; Long, J. R.; You, X.-Z. Angew. Chem., Int. Ed. 2004, 43, 5940-5943.

(52) view "Pseudooctahedral Complexes of Vanadium(III): Electronic Structure Investigation by Magnetic and Electronic Spectroscopy" Krzystek, J.; Fiedler, A. T.; Sokol, J. J.; Ozarowski, A.; Zvyagin, S. A.; Brunold, T. C.; Long, J. R.;Brunnel, L.-C.; Telser, J. Inorg. Chem. 2004, 43, 5645-5658.

(51) view "Raising the Spin-Reversal Barrier in Cyano-Bridged Single-Molecule Magnets: Linear MnIII2MIII(CN)6 (M = Cr, Fe) Species Incorporating [(5-Brsalen)Mn]+ Units" Choi, H. J.; Sokol, J. J.; Long, J. R. Inorg. Chem. 2004, 43, 1606-1608.

(50) view "High-Spin Metal-Cyanide Clusters: Species incorporating [Mn(salen)]+ Complexes as a Source of Anisotropy" Choi, H. J.; Sokol, J. J.; Long, J. R. J. Phys. Chem. Solids 2004, 65, 839-844.

(49) view "Trimethyltriazacyclononanechromium(III) Complexes and a Chromium(III)-Nickel(II)-Cyanide Cluster with a Face-Centered Cubic Geometry" Shores, M. P.; Berseth, P. A.; Long, J. R. Inorg. Syn. 2004, 34, 149-155.

(48) view "Cluster-to-Metal Magnetic Coupling: Synthesis and Characterization of 25-Electron [Re6-nOsnSe8(CN)6](5-n)- (n = 1, 2) Clusters and {Re6-nOsnSe8[CNCu(Me6tren)]6}9+ (n = 0, 1, 2) Assemblies" Tulsky, E. G.; Crawford, N. R. M.;Baudron, S. A.; Batail, P; Long, J. R. J. Am. Chem. Soc. 2003, 125, 15543-15553.

(47) view "New Routes to Transition Metal-Carbido Species: Synthesis and Characterization of the Carbon-Centered Trigonal Prismatic Clusters [W6CCl18]n- (n = 1, 2, 3)" Welch, E. J.; Crawford, N. R. M.; Bergman, R. G.; Long, J. R. J. Am. Chem. Soc. 2003, 125, 11464-11465.

(46) view "Synthesis and Characterization of a Decacobalt Carbonyl Cluster with Two Semi-Interstitial Phosphorus Atoms" Hong, C. S.; Berben, L. A.; Long, J. R. Dalton Trans. 2003, 2119-2120.

(45) view "Molecular Cluster Magnets" Long, J. R. In Chemistry of Nanostructured Materials; Yang, P., Ed.; World Scientific, Hong Kong, 2003, pp. 291-315.

(44) view "New Cyanometalate Building Units: Synthesis and Characterization of [Re(CN)7]3- and [Re(CN)8]3-" Bennett, M. V.; Long, J. R. J. Am. Chem. Soc. 2003, 125, 2394-2395.

(43) view "High-Nuclearity Metal-Cyanide Clusters: Synthesis, Magnetic Properties, and Inclusion Behavior of Open Cage Species Incorporating [(tach)M(CN)3] (M = Cr, Fe, Co) Complexes" Yang, J. Y.; Shores, M. P.; Sokol, J. J.; Long, J. R. Inorg. Chem. 2003, 42, 1403-1419.

(42) view "Cluster Synthesis via Ligand-Arrested Solid Growth: Triethylphosphine-Capped Fragments of Binary MetalChalcogenides" Crawford, N. R. M.; Hee, A. G.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 14842-14843.

(41) view "Co3[Co(CN)5]2 A Microporous Magnet with an Ordering Temperature of 38 K" Beauvais, L. G.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 12096-12097.

(40) view "Synthesis and Alkali Metal Ion-Binding Properties of a Chromium(III) Triacetylide Complex" Berben, L. A.; Long, J. R.J. Am. Chem. Soc. 2002, 124, 11588-11589.

(39) view "[(Cyclen)4Ru4(pz)4]9+: A Creutz-Taube Square" Lau, V. C.; Berben, L. A.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 9042-9043.

(38) view "A Cyano-Bridged Single-Molecule Magnet: Slow Magnetic Relaxation in a Trigonal Prismatic MnMo6(CN)18 Cluster" Sokol, J. J.; Hee, A. G.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 7656-7657.

(37) view "Kondo Resonance in a Single-Molecule Transistor" Liang, W.; Shores, M. P.; Bockrath, M.; Long, J. R.; Park, H. Nature 2002, 417, 725-729.

(36) view "Giant Metal-Cyanide Coordination Clusters: Tetracapped Edge-Bridged Cubic Cr12Ni12(CN)48 and Double Face-Centered Cubic Cr14Ni13(CN)48 Species" Sokol, J. J.; Shores, M. P.; Long, J. R. Inorg. Chem. 2002, 41, 3052-3054.

(35) view "Tetracyanide-Bridged Divanadium Complexes: Redox Switching Between Strong Antiferromagnetic and Strong Ferromagnetic Coupling" Shores, M. P.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 3512-3513.

(34) view "Nickel(II)-Molybdenum(III)-Cyanide Clusters: Synthesis and Magnetic Behavior of Species Incorporating [(Me3tacn)Mo(CN)3]" Shores, M. P.; Sokol, J. J.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 2279-2292.

(33) view "Cyanide-Limited Complexation of Molybdenum(III): Synthesis of Octahedral [Mo(CN)6]3- and Cyano-Bridged [Mo2(CN)11]5-" Beauvais, L. G.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 2110-2111.

(32) view "Heterometal Substitution in the Dimensional Reduction of Cluster Frameworks: Synthesis of Soluble [Re6-nOsnSe8Cl6]4-n (n = 1, 2, 3) Cluster-Containing Solids" Tulsky, E. G.; Long, J. R. Inorg. Chem. 2001, 40, 6990-7002.

(31) view "Expanded Prussian Blue Analogues Incorporating [Re6Se8(CN)6]3-/4- Clusters: Adjusting Porosity via Charge Balance" Bennett, M. V.; Beauvais, L. G.; Shores, M. P.; Long, J. R. J. Am. Chem. Soc. 2001, 123, 8022-8032.

(30) view "Edge-Bridged Octahedral Tungsten-Oxygen-Chlorine Clusters: Synthesis and Characterization of Two D3d -Symmetric [W6O6Cl12]2- Isomers and [W6O7Cl11]3-" Crawford, N. R. M.; Long, J. R. Inorg. Chem. 2001, 40, 3456-3462.

(29) view "Manganese-Chromium-Cyanide Clusters: Molecular MnCr6(CN)18 and Mn3Cr6(CN)18 Species and a Related MnCr3(CN)9 Chain Compound" Heinrich, J. L.; Sokol, J. J.; Hee, A. G.; Long, J. R. J. Solid State Chem. 2001, 159, 293-301.

(28) view "Dimensional Reduction: A Practical Formalism for Manipulating Solid Structures" Tulsky, E. G.; Long, J. R. Chem. Mater. 2001, 13, 1149-1166.

(27) view "High-Nuclearity Chromium-Nickel-Cyanide Clusters: An Open Cr8Ni5(CN)24 Cage and a C3-Symmetric Cr10Ni9(CN)42 Cluster Incorporating Three Forms of Cyanonickelate" Sokol, J. J.; Shores, M. P.; Long, J. R. Angew. Chem. Int. Ed. 2001, 40, 236-239.

(26) view "High-Nuclearity Metal-Cyanide Clusters: Assembly of a Cr8Ni6(CN)24 Cage with a Face-Centered Cubic Geometry"Berseth, P. A.; Sokol, J. J.; Shores, M. P.; Heinrich, J. L.; Long, J. R. J. Am. Chem. Soc. 2000, 122, 9655-9662.

(25) view "Expansion of the Porous Solid Na2Zn3[Fe(CN)6]2·9H2O: Enhanced Ion-Exchange Capacity in Na2Zn3[Re6Se8(CN)6]2·24H2O" Bennett, M. V.; Shores, M. P.; Beauvais, L. G.; Long, J. R. J. Am. Chem. Soc. 2000, 122, 6664-6668.

(24) view "Oxygenation of Hydrocarbons Mediated by Mixed-Valent Basic Iron Trifluoroacetate and Valence-Seperated Component Species under Gif-Type Conditions Involves Carbon- and Oxygen-Centered Radicals" Tapper, A. E.; Long, J. R.; Staples, R. J.; Stavropoulos, P. Angew. Chem. Int. Ed. 2000, 39, 2343-2346.

(23) view "Cyano-Bridged Re6Q8 (Q = S, Se) Cluster-Cobalt(II) Framework Materials: Versatile Solid Chemical Sensors" Beauvais, L. G.; Shores, M. P.; Long, J. R. J. Am. Chem. Soc. 2000, 122, 2763-2772.

(22) view "[Cd2(H2O)4][Re6S8(CN)6]·14H2O: A Cyano-Bridged Cluster-Cluster Framework Solid with Accessible CubelikeCavities" Shores, M. P.; Beauvais, L. G.; Long, J. R. Inorg. Chem. 1999, 38, 1648-1649.

(21) view "Cluster-Expanded Prussian Blue Analogues" Shores, M. P.; Beauvais, L. G.; Long, J. R. J. Am. Chem. Soc. 1999, 121, 775-779.

(20) view "Cyano-Bridged Re6Q8 (Q = S, Se) Cluster-Metal Framework Solids: A New Class of Porous Materials" Beauvais, L. G.; Shores, M. P.; Long, J. R. Chem. Mater. 1998, 10, 3783-3786.

(19) view "Molecular Prussian Blue Analogues: Synthesis and Structure of Cubic Cr4Co4(CN)12 and Co8(CN)12 Clusters" Heinrich, J. L.; Berseth, P. A.; Long, J. R. Chem. Commun. 1998, 1231-1232.

(18) view "Polynuclear Complexes of Copper(I) and the 2-(3(5)-Pyrazolyl),6-methylpyridine Ligand: Structures and Reactivity Toward Small Molecules" Singh, K.; Long, J. R.; Stavropoulos, P. Inorg. Chem. 1998, 37, 1073-1079.

(17) view "Ligand Substitution Reactions of [Re6S8Br6]4-: A Basis Set of Re6S8 Clusters for Building Multicluster Assemblies"Willer, M. W.; Long, J. R.; McLauchlan, C. C.; Holm, R. H. Inorg. Chem. 1998, 37, 328-333.

(16) view "Evidence for Cu…H Interactions in Dinuclear Cu(I) Complexes of Hindered Hydrotris(pyrazolyl)borate Ligands" Kiani, S.; Long, J. R.; Stavropoulos, P. Inorg. Chim. Acta 1997, 263, 357-366.

(15) view "Synthesis, Reactivity and Catalytic Behavior of Fe/Zn-Containing Species Involved in Oxidation of Hydrocarbons under Gif-Type Conditions" Singh, B.; Long, J. R.; Fabrizi de Biani, F.; Gatteschi, D.; Stavropoulos, P. J. Am. Chem. Soc. 1997, 119, 7030-7047.

(14) view "Ligand-Unsupported Metal-Metal (M = Cu, Ag) Interactions Between Closed-Shell d10 Trinuclear Systems" Singh, K.; Long, J. R.; Stavropoulos, P. J. Am. Chem. Soc. 1997, 119, 2942-2943.

(13) view "A Basis Set of Re6Se8 Cluster Building Blocks and Demonstration of Their Linking Capability: Directed Synthesis of an Re12Se16 Dicluster" Zheng, Z.; Long, J. R.; Holm, R. H. J. Am. Chem. Soc. 1997, 119, 2163-2171.

(12) view "Polycubane Clusters: Synthesis of [Fe4S4(PR3)4]1+,0 (R = But, Cy, Pri) and [Fe4S4]0 Core Aggregation Upon Loss of Phosphine" Goh, C.; Segal, B. M.; Huang, J.; Long, J. R.; Holm, R. H. J. Am. Chem. Soc. 1996, 118, 11844-11853.

(11) view "Synthesis and Characterization of Four Consecutive Members of the Five-Member [Fe6S8(PEt3)6]n+ (n = 0 - 4) Cluster Electron Transfer Series" Goddard, C. A.; Long, J. R.; Holm, R. H. Inorg. Chem. 1996, 35, 4347-4354.

(10) view "On the Reduction of Basic Iron Acetate: Isolation of Ferrous Species Mediating Gif-Type Oxidation of Hydrocarbons" Singh, B.; Long, J. R.; Papaefthymiou, G. C.; Stavropoulos, P. J. Am. Chem. Soc. 1996, 118, 5824-5825.

(09) view "A Solid State Route to Molecular Clusters: Access to the Solution Chemistry of [Re6Q8]2+ (Q = S, Se) Core-Containing Clusters via Dimensional Reduction" Long, J. R.; McCarty, L. S.; Holm, R. H. J. Am. Chem. Soc. 1996, 118, 4603-4616.

(08) view "Octanuclear Iron-Sulfur Clusters with Symmetrically Coupled Fe4S4 and Fe4S5 Cores" Cai, L.; Segal, B. M.; Long, J. R.; Scott, M. J.; Holm, R. H. J. Am. Chem. Soc. 1995, 117, 8863-8864.

(07) view "Comprehensive Tungsten-Iodine Cluster Chemistry: Isolated Intermediates in the Solid State Nucleation of [W6I14]2-" Franolic, J. D.; Long, J. R.; Holm, R. H. J. Am. Chem. Soc. 1995, 117, 8139-8153.

(06) view "Dimensional Reduction of Re6Se8Cl2: Sheets, Chains and Discrete Clusters Composed of Chloride-Terminated [Re6Q8]2+ (Q = S, Se) Cores" Long, J. R.; Williamson, A. S.; Holm, R. H. Angew. Chem. 1995, 107, 248-251; Angew. Chem., Int. Ed. Engl. 1995, 34, 226-229.

(05) view "Protein-Bound Iron-Sulfur Clusters: Application of a Structural Database" Long, J. R.; Holm, R. H. Inorg. Chim. Acta. 1995, 229, 229-239.

(04) view "Enumeration and Structural Classification of Clusters Derived from Parent Solids: Metal-Chalcogenide Clusters Composed of Edge-Sharing Tetrahedra" Long, J. R.; Holm, R. H. J. Am. Chem. Soc. 1994, 116, 9987-10002.

(03) view "SmF64- Conformation Caused by 5d-2p Orbital Interactions" Dronskowski, R.; Köhler, J.; Long, J. R. J. Phys. Chem. Solids 1993, 54, 801-808.

(02) view Structural Preferences Among the Rare Earth Dicarbides: The Electronic Structure of LaC2 and ThC2 " Long, J. R.;Halet, J.-F.; Saillard, J.-Y.; Hoffmann, R.; Meyer, H.-J. New J. Chem. 1992, 16, 839-846.

(01) view "Distortions in the Structure of Calcium Carbide: A Theoretical Investigation" Long, J. R.; Hoffmann, R.; Meyer, H.-J. Inorg. Chem. 1992, 31, 1734-1740.